Diffusion-Flame Extinction in the Stagnation-Point Boundary Layer of PMMA in O2/N2Mixtures
作者:
L. KRISHNAMURTHY,
期刊:
Combustion Science and Technology
(Taylor Available online 1975)
卷期:
Volume 10,
issue 1-2
页码: 21-25
ISSN:0010-2202
年代: 1975
DOI:10.1080/00102207508946654
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Experimental results on the gas-phase extinction of diffusion flame for the pyrolyzed products of PMMA (polymethylmethacrylate) rods burning in laminar flows of O2/Nj mixtures are reported. Critical extinction conditions in terms of oxygen concentration, oxidizer mass flux and pressure are established. Kinetic parameters for the overall gas-phase oxidation process have been obtained from these results with the aid of recently-developed theoretical analyses for extinction of diffusion flames in the stagnation-point boundary layer of condensed fuels. Thus, on the basis of an overall reaction of order one with respect to oxygen and one with respect to PMMA-pyrolysis products, the experimental results provide values of 21 kcal/mole for the overall activation energy and of 3 × 1012cm5/ mole sec for the preexponential factor.
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