首页   按字顺浏览 期刊浏览 卷期浏览 A comment on the estimation of random branching from viscosity measurements
A comment on the estimation of random branching from viscosity measurements

 

作者: Libuše Mrkvičková,   Otakar Quadrat,  

 

期刊: Die Makromolekulare Chemie  (WILEY Available online 1982)
卷期: Volume 183, issue 9  

页码: 2173-2182

 

ISSN:0025-116X

 

年代: 1982

 

DOI:10.1002/macp.1982.021830914

 

出版商: Hüthig&Wepf Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe hydrodynamic behaviour of polydisperse branched copolymers of methyl methacrylate with a small amount of ethylene dimethacrylate was investigated in several solvents possessing different “solvent power”. It was found that with increasing degree of branching the viscometric expansion coeficient α 3[η],bof these copolymers decreases compared with the expansion of the linear analogs α 3[η],l(before the gel point α 3[η],b/α 3[η],l≈ 0,5). This phenomenon is demonstrated to be useful in the application of viscometry as a method of estimation or deter

 

点击下载:  PDF (387KB)



返 回