A comment on the estimation of random branching from viscosity measurements
作者:
Libuše Mrkvičková,
Otakar Quadrat,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 9
页码: 2173-2182
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830914
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe hydrodynamic behaviour of polydisperse branched copolymers of methyl methacrylate with a small amount of ethylene dimethacrylate was investigated in several solvents possessing different “solvent power”. It was found that with increasing degree of branching the viscometric expansion coeficient α 3[η],bof these copolymers decreases compared with the expansion of the linear analogs α 3[η],l(before the gel point α 3[η],b/α 3[η],l≈ 0,5). This phenomenon is demonstrated to be useful in the application of viscometry as a method of estimation or deter
点击下载:
PDF
(387KB)
返 回