首页   按字顺浏览 期刊浏览 卷期浏览 The Kinetics of Reduction of Sulfoxides by the Iodide Ion in Aqueous Perchloric Acid
The Kinetics of Reduction of Sulfoxides by the Iodide Ion in Aqueous Perchloric Acid

 

作者: Ludmilla Cermakova,   Jarmila Hamplova,  

 

期刊: Analytical Letters  （Taylor Available online 1971）
卷期: Volume 4, issue 9  

页码: 631-639

 

ISSN:0003-2719

 

年代: 1971

 

DOI:10.1080/00032717108058660

 

出版商: Taylor & Francis Group

 

关键词: kinetic measurements;sulfoxides;redox-reaction;iodide

 

数据来源: Taylor

 

摘要:

The kinetics of the acid-catalyzed reactions of di-n-butyl -sulfoxide (BuSOBu), di-phenylsulfoxide (PhSOPh), and di-benzyl -sulfoxide (PhCH2SOCH2Ph) with iodide in a medium of HCLO4has been followed; the reaction orders with respect to sulfoxide and iodide have been determined and a possible mechanism discussed.

 

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