ESCA investigation of the electronic structure of polyhexafluorobut‐2‐yne
作者:
R. D. Chambers,
D. T. Clark,
D. Kilcast,
S. Partington,
期刊:
Journal of Polymer Science: Polymer Chemistry Edition
(WILEY Available online 1974)
卷期:
Volume 12,
issue 8
页码: 1647-1652
ISSN:0360-6376
年代: 1974
DOI:10.1002/pol.1974.170120805
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractPolyperfluorobut‐2‐yne is prepared by a fluoride ion‐induced polymerization of hexafluorobut‐2‐yne. The mass spectrum indicates a regular fragmentation pattern but the ESCA spectrum establishes the structure as a polyene, rather than a crosslinked system, and the occurrence of a shake‐up peak assists in this
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