Properties of Molecular-Based Frustrated Magnets
作者:
C.M. Wynn,
A.S. Albrecht,
C.P. Landee,
C. Navas,
M.M. Turnbull,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 274,
issue 1
页码: 1-10
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508031859
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The magnetic properties of cobalt complexes of BTCA (BTCA = 1,3,5 benzenetricarboxylic acid) have been investigated. The trianion of the BTCA ligand has the ability to create lattices with competing interactions leading to frustration. A dodecahydrate phase, Co3BTCA2(H2O)12, is obtained from room temperature aqueous solutions and consists of pendant chains with very small interactions. Varying the reaction conditions leads to an amorphous phase which displays many of the features of a spin glass: hysteresis, remanent magnetization, frequency dependent susceptibility, aging effects, and an inverse field dependence of the dc susceptibility. The dehydration state and corresponding magnetic properties are strongly dependent on the temperature of the original reaction. Reaction temperatures below 78 °C lead to the pendant chain while temperatures greater than 78 °C yield more interesting glassy phases. These phases exhibit many properties of reentrant spin glasses.
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