Cartesian Dynamics of Simple Molecules VIII planar quadratomics (D3hsymmetry)
作者:
S.X. Weng,
O.S. Binbrek,
A. Anderson,
期刊:
Spectroscopy Letters
(Taylor Available online 1991)
卷期:
Volume 24,
issue 7-8
页码: 959-973
ISSN:0038-7010
年代: 1991
DOI:10.1080/00387019108020675
出版商: Taylor & Francis Group
关键词: Molecular vibrations;infrared spectroscopy;Raman spectroscopy;lattice dynamics
数据来源: Taylor
摘要:
The vibrations of planar A3B type molecules with D3hsymmetry are analysed, by treating these molecules as a special case of A2BC types with C2vsymmetry. Analytical expressions for the four normal mode frequencies are derived in terms of four force constants, and optimized values of the latter for the boron trihalides and sulphur trioxide are obtained and briefly discussed. Frequencies of various isotopic species are also calculated.
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