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Raman spectra of fluid nitrogen: intermolecular torques and orientational correlation times†

 

作者: A. de Santis,   M. Nardone,   M. Sampoli,   P. Morales,   G. Signorelli,  

 

期刊: Molecular Physics  (Taylor Available online 1980)
卷期: Volume 39, issue 4  

页码: 913-921

 

ISSN:0026-8976

 

年代: 1980

 

DOI:10.1080/00268978000100781

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A comparison is made between the rotovibrational Raman bands of fluid nitrogen at room temperature in the 180–355 amagat density range and the corresponding pure rotational bands reported previously. Accurate moment values are derived from the Raman spectra, accounting for the response of the entire experimental apparatus, after subtraction of the unwanted isotope band and of the leaking polarizedQbranch. Correlation times are also calculated for both rotovibrational and pure rotational spectra accounting for the finite instrumental slitwidth.

 

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