Raman spectra of fluid nitrogen: intermolecular torques and orientational correlation times†
作者:
A. de Santis,
M. Nardone,
M. Sampoli,
P. Morales,
G. Signorelli,
期刊:
Molecular Physics
(Taylor Available online 1980)
卷期:
Volume 39,
issue 4
页码: 913-921
ISSN:0026-8976
年代: 1980
DOI:10.1080/00268978000100781
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A comparison is made between the rotovibrational Raman bands of fluid nitrogen at room temperature in the 180–355 amagat density range and the corresponding pure rotational bands reported previously. Accurate moment values are derived from the Raman spectra, accounting for the response of the entire experimental apparatus, after subtraction of the unwanted isotope band and of the leaking polarizedQbranch. Correlation times are also calculated for both rotovibrational and pure rotational spectra accounting for the finite instrumental slitwidth.
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