Phase behavior of gradient copolymers
作者:
Aleksij Aksimentiev,
Robert Holyst,
期刊:
AIP Conference Proceedings
(AIP Available online 1900)
卷期:
Volume 519,
issue 1
页码: 71-77
ISSN:0094-243X
年代: 1900
DOI:10.1063/1.1291523
出版商: AIP
数据来源: AIP
摘要:
Phase properties of gradientABcopolymer melts which consist of chains with the specified chemical distribution ofAandBmonomers have been studied within the Landau-Ginzburg model. All the melts with the linear distribution of the monomers exhibit only a direct continuous phase transition from disordered to the lamellar phase. The hexagonal, body-centered-cubic, double-gyroid(G) and lamellar ordered structures have been found in the melts with the monotonic but nonlinear distribution of the monomers. The G structure has been also found in the gradient copolymer melts with the distribution function of monomers similar to theA−B−Atriblock copolymers. ©2000 American Institute of Physics.
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