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Phase behavior of gradient copolymers

 

作者: Aleksij Aksimentiev,   Robert Holyst,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1900)
卷期: Volume 519, issue 1  

页码: 71-77

 

ISSN:0094-243X

 

年代: 1900

 

DOI:10.1063/1.1291523

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Phase properties of gradientABcopolymer melts which consist of chains with the specified chemical distribution ofAandBmonomers have been studied within the Landau-Ginzburg model. All the melts with the linear distribution of the monomers exhibit only a direct continuous phase transition from disordered to the lamellar phase. The hexagonal, body-centered-cubic, double-gyroid(G) and lamellar ordered structures have been found in the melts with the monotonic but nonlinear distribution of the monomers. The G structure has been also found in the gradient copolymer melts with the distribution function of monomers similar to theA−B−Atriblock copolymers. ©2000 American Institute of Physics.

 

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