The Behaviour of a Fluid Mixture in Contact with a Surface
作者:
M.J. Stott,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1997)
卷期:
Volume 34,
issue 3
页码: 155-167
ISSN:0031-9104
年代: 1997
DOI:10.1080/00319109708030559
出版商: Taylor & Francis Group
关键词: Hard spheres;Percus-Yevick method;binary mixture
数据来源: Taylor
摘要:
The behaviour of a fluid mixture near a structureless hard wall is investigated. Following earlier work [D. Henderson, F. F. Abraham and J. A. Barker, Molec. Phys.31, 1291 (1976)] we consider the limiting case of a fluid mixture in which one of the species, representing the wall, is dilute and infinitely large. In this limit the Ornstein-Zernike equations yield the density distributions of each of the components with respect to the hard wall. The specific case of a mixture of hard spheres in contact with a hard wall is treated within the Percus-Yevick approximation and explicit results are obtained for a binary mixture. In addition to the density distributions simple expressions are obtained for the integrated densities. The density fluctuations in the fluid near the wall are small and short ranged for the hard sphere fluid. The effects of tails to the interatomic potentials outside the hard spheres can be incorporated approximately and could lead to much larger fluctuations in the densities.
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