Acceptors in Donor‐Doped GaAs Resulting from Li Diffusion
作者:
C. S. Fuller,
K. B. Wolfstirn,
期刊:
Journal of Applied Physics
(AIP Available online 1963)
卷期:
Volume 34,
issue 7
页码: 1914-1920
ISSN:0021-8979
年代: 1963
DOI:10.1063/1.1729712
出版商: AIP
数据来源: AIP
摘要:
Experiments have been carried out on Te‐doped (∼1–3×1018cm−3) GaAs crystals in which changes innare measured when Li is introduced by diffusion and again after the Li is removed. The amounts of Li removed are determined by chemical analyses. It is found that two Li atoms introduced cause a loss of one electron, corresponding to a (Li+Li=) pair. Acceptors remain during the removal of Li which are postulated to be Ga vacancies. The kinetics of the disappearance of the ``vacancies'' have been investigated. The process appears to be diffusion controlled with an activation energy corresponding to 5–6 eV. The equilibria reached show an increasing ``vacancy'' solubility with decreasing temperature. A model in which Ga vacancies form stable pairs with Te atoms is discussed.
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