Hydrolytic polymerization of caprolactam. II. Vapor–liquid equilibria
作者:
C. Giori,
B. T. Hayes,
期刊:
Journal of Polymer Science Part A‐1: Polymer Chemistry
(WILEY Available online 1970)
卷期:
Volume 8,
issue 2
页码: 351-358
ISSN:0449-296X
年代: 1970
DOI:10.1002/pol.1970.150080207
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThe system water–caprolactam–polymer at equilibrium is regarded as a solution consisting of two solvents (water and caprolactam) and one solute (polymer). The activities of water and caprolactam in equilibrium at 270°C in the range of 2–10 wt‐% total water content have been determined by vapor‐pressure measurements. Water shows large negative deviations from Raoult's law, as a consequence of the different size of water and polymer molecules. The partial molar free energies of mixing are compared with the expressions derived from the Flory‐Huggins theory of polymer solutions; the results are not conclusive, but seem to indicate a qualitative agreement with the theory. The increase in vapor pressure during polymerization in sealed systems and the water dependence of the polycondensation equilibrium are discussed and explained in terms of water acti
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