Hindered rotation of adsorbed diatomic molecules
作者:
T.B. MacRury,
J.R. Sams,
期刊:
Molecular Physics
(Taylor Available online 1971)
卷期:
Volume 20,
issue 1
页码: 57-66
ISSN:0026-8976
年代: 1971
DOI:10.1080/00268977100100071
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Ortho-para separation factors for H2and D2are discussed in terms of two models of hindered rotation in the adsorbed phase. Although the available experimental data do not provide a definitive test of the models, it appears that both rotational modes are perturbed, and that a model incorporating hindrance of both modes is capable of fitting both the observed magnitude and temperature dependence of the separation factors.
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