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Analytical solutions for rotational diffusion in the mean field potential: application to the theory of dielectric relaxation in nematic liquid crystals

 

作者: YURI P. KALMYKOV,   WILLIAM T. COFFEY,  

 

期刊: Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 25, issue 3  

页码: 329-339

 

ISSN:0267-8292

 

年代: 1998

 

DOI:10.1080/026782998206128

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A theory of dielectric relaxation in nematics is developed for a molecular dipole moment directed at an arbitrary angle to the molecular long axis. Both exact and simple approximate analytical formulae for the longitudinal and transverse components of the complex dielectric permittivity tensor are obtained for the non-inertial rotational Brownian motion of a molecule in the mean field potential of Maier and Saupe. It appears that both longitudinal and transverse relaxation processes are effectively described by two Debye type mechanisms with corresponding relaxation times and dielectric strengths expressed in terms of the order parameter. The generalization of the theory for an arbitrary axially symmetric mean field potential is given.

 

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