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Remanence polarity effects on hydrogen damage of ferroelectric thin film capacitors

 

作者: StevenD. Traynor,   Shan Sun,   Domokos Hadnagy,  

 

期刊: Integrated Ferroelectrics  (Taylor Available online 1999)
卷期: Volume 27, issue 1-4  

页码: 195-203

 

ISSN:1058-4587

 

年代: 1999

 

DOI:10.1080/10584589908228468

 

出版商: Taylor & Francis Group

 

关键词: Ferroelectric capacitors;PLZT;integration;polarity;hydrogen

 

数据来源: Taylor

 

摘要:

Ferroelectric properties of metal/ferroelectric/metal capacitors can be severely degraded during FRAM® integration in a hydrogen containing ambient. To understand the mechanism of hydrogen damage we characterized ferroelectric capacitors with the configuration of Pt/PLZT/Pt and Pt/SBTN/Pt annealed in the temperature range of 50°C to 200°C using hysteresis and DC pulsing. The capacitors were stored in specific remanent states (negative, positive, and zero) by poling prior to annealing. The annealing was carried out in a forming gas ambient, containing 1% hydrogen and 99% nitrogen. The degradation is strongly dependent on the polarity of the remanent polarization. From the results, we propose an empirical model of the formation of a fixed dipole layer at the top electrode-ferroelectric interface and we confirm that the polarity of this charge is positive.

 

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