This investigation is concerned with the development of a low‐inductance, low‐jitter, electrically triggered, high‐voltage annular rail spark gap. Three trigger electrode geometries—blade, dull, and sawtooth edge—are tested for the effects of different field stresses on the spark gap switching performance. All possible polarity combinations are applied to the high‐voltage and trigger electrodes of the rail gap, and the switching inductance and jitter is measured for each case. Finally, the effects of photopreionization from bare sparks on the spark gap switching performance is explored. A switch inductance of 4 nH and jitter of 0.6 ns have been achieved. A practical application of the rail gap is also described.