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Sequence control on the ring‐opening oligomerization of cyclic imino ethers

 

作者: Keigo Aoi,   Masahiko Okada,   Masatoshi Miyamoto,  

 

期刊: Macromolecular Rapid Communications  (WILEY Available online 1997)
卷期: Volume 18, issue 1  

页码: 17-21

 

ISSN:1022-1336

 

年代: 1997

 

DOI:10.1002/marc.1997.030180103

 

出版商: Hüthig&Wepf Verlag

 

数据来源: WILEY

 

摘要:

AbstractSequence‐controlled oligomers of cyclic imino ethers were synthesized by the one‐pot multi‐stage feeding method. Selective formation of the sequence was clearly demonstrated by equimolar reactions between the monomers and 1:1 adducts of an initiator with the monomers. Efficiency of the sequence control is determined by the difference of reactivities of the active ends. A new general prerequisite to synthesize a well‐defined sequence by multi‐stage oligomerization was

 

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