Segmental distribution in amorphous polymers as elucidated from crystallization and relaxation times
作者:
ShaulM. Aharoni,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1977)
卷期:
Volume 13,
issue 1
页码: 159-172
ISSN:0022-2348
年代: 1977
DOI:10.1080/00222347708208760
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
It is shown by various means that a significant amount of order exists in the crystalline bulk and in the fold surfaces of lamellar crystals crystallized from the supercooled melt. Analysis of viscoelastic relaxation times and isothermal crystallization rates leads to the conclusion that lamellar crystals showing a significant measure of internal and fold surface order are incompatible with the existence of Gaussian random coils in the supercooled polymeric melt.
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