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Raman Study of the Effect of NaClO4and NaI on the Hydrogen-Bonded Structure of Liquid NH3

 

作者: J.H. Roberts,   A.T. Lemley,   J.J. Lagowski,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1972)
卷期: Volume 5, issue 8  

页码: 271-274

 

ISSN:0038-7010

 

年代: 1972

 

DOI:10.1080/00387017208064963

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Recent studies1,2of the Raman spectra of liquid ammonia have been in disagreement with regard to the assignment of bands in the 3000 cm−1region. This region is complicated by Fermi resonance between the ν1(A1) fundamental stretching mode and the 2ν4(A1) overtone of the bending mode. In an effort to help clarify these assignments and to study further the structure of liquid ammonia, it was decided to measure the Raman spectrum of several salt solutions in liquid ammonia.

 

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