THE EXCHANGE OF IODINE BETWEEN INORGANIC IODIDES ANDn-BUTYL IODIDE
作者:
G. W. Hodgson,
H. G. V. Evans,
C. A. Winkler,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1951)
卷期:
Volume 29,
issue 1
页码: 60-69
ISSN:0008-4042
年代: 1951
DOI:10.1139/v51-008
出版商: NRC Research Press
数据来源: NRC
摘要:
Lithium, sodium, and caesium iodides are highly ionized in acetonitrile solution and have practically the same rates and activation energies (18 kcal. per mole) for their exchange reactions withn-butyl iodide in this solvent. There seems little doubt, therefore, that these exchange reactions occur between the organic iodide and iodide ion derived from the inorganic salt. Zinc and cadmium iodides, and iodine, are only slightly ionized in acetonitrile and exchange withn-butyl iodide with rates that are widely different from one another and from the rate of iodide ion exchange. The activation energies are 21.9, 20.6, and 17.5 kcal. per mole respectively. It is concluded that these exchange reactions involve predominantly complex ions.
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