Vibronic coupling in cubic complexes
作者:
O. Kahn,
S.F.A. Kettle,
期刊:
Molecular Physics
(Taylor Available online 1975)
卷期:
Volume 29,
issue 1
页码: 61-79
ISSN:0026-8976
年代: 1975
DOI:10.1080/00268977500100061
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This paper examines the consequences of a strong vibronic coupling on orbitally triply degenerate levels in a cubic environment for the three cases in which spin-orbit coupling is weaker than, comparable with, or stronger than the vibronic coupling. It is shown that vibronic orbital reduction factors may be strongly temperature dependent. The consequences of this temperature dependence for the interpretation of magnetic susceptibility measurements are briefly discussed. An Appendix details a method for the evaluation of overlap integrals between harmonic oscillator eigenfunctions.
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