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IR-spektroskopische und mechanistische Untersuchungen an Technetiumkomplexen unter Einsatz von15N

 

作者: B. Lorenz,   K. Schmidt,   L. Kaden,   M. Wahren,  

 

期刊: Isotopenpraxis Isotopes in Environmental and Health Studies  （Taylor Available online 1986）
卷期: Volume 22, issue 12  

页码: 444-446

 

ISSN:0021-1915

 

年代: 1986

 

DOI:10.1080/10256018608623723

 

出版商: Taylor & Francis Group

 

关键词: azides;chemical preparation;hydrazine;infrared spectra;nitrogen 15;technetium 99;technetium complexes

 

数据来源: Taylor

 

摘要:

The formation of Technetium nitrido- and thionitrosyl-complexes was investigated by means of15N labelled compounds. The course of the reaction is rather different with the elements technetium and rhenium in spite of quite analogous starting materials and products. A new feasible synthesis of nitridotechnetium (V) complexes was found from complexes of Te(III) and azide. By15N-substitution an unambiguous assignment of characteristic infrared bonds in the complexes was achieved.

 

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