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Synthesis of Conjugated Optically Active Polymetallocenes

 

作者: ThomasJ. Katz,   Anantha Sudhakar,   Bingwei Yang,   JamesS. Nowick,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1989)
卷期: Volume 26, issue 2-3  

页码: 309-326

 

ISSN:0022-233X

 

年代: 1989

 

DOI:10.1080/00222338908051976

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The development of methodology for synthesizing new materials in which metal atoms are linked by hydrocarbons whose electronic conjugation is unbroken is described. The fundamental idea is to twist the hydrocarbons into helices. By attaching bulky groups to their precursors, the helices can be made to twist mainly in one direction. The molecules synthesized are helicenes capped by five-membered rings to which metals are attached. If the size of the helix is chosen appropriately, a polymeric structure forms in which hydrocarbon rings and metal atoms alternate. An oligomer with Structure22is the first such material prepared. It and related structures might be precursors of molecular solenoids, examples of which are not yet known.

 

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