Compact Swelling in Bi1.4Pb0.6Sr2Ca2Cu3.6OyDuring the Formation of High‐TcSuperconducting Phase
作者:
Chan Joong Kim,
Suk‐Joong L. Kang,
Dong‐Yeon Won,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1992)
卷期:
Volume 75,
issue 3
页码: 570-574
ISSN:0002-7820
年代: 1992
DOI:10.1111/j.1151-2916.1992.tb07844.x
出版商: Blackwell Publishing Ltd
关键词: lead;doping;superconductors;growth;swelling
数据来源: WILEY
摘要:
Compact swelling in Pb‐doped Bi‐Sr‐Ca‐Cu‐O superconductor has been studied by observing the effects of the size of calcined powders, volatilization of materials, and sintering of high‐Tc(2223) powders. The bulk density increases at the early stage of sintering, for about 20 h, and then decreases. Densification occurs when the low‐Tc(2212) phase and a liquid phase exist, whereas dedensification occurs with the formation of the 2223 phase regardless of the presence of the liquid. Gas evolution from specimens does not appear to be responsible for compact swelling. Compact swelling is explained by anisotropic growth of thin, platelike 2223 grains in random orientation. When 2223 grains grow in a preferred direction, compact swelling
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