Characterization of Coulometric and Hypercoulometric ECD Mode of Operation
作者:
P. Popp,
J. Leonhardt,
期刊:
Isotopenpraxis Isotopes in Environmental and Health Studies
(Taylor Available online 1983)
卷期:
Volume 19,
issue 5
页码: 160-162
ISSN:0021-1915
年代: 1983
DOI:10.1080/10256018308544871
出版商: Taylor & Francis Group
关键词: electron capture;electron-capture detectors;environment;gas chromatography;space charge;radiation sources
数据来源: Taylor
摘要:
The coulometric mode of operation is given, if each sample molecule passing the ECD is converted into a negative ion and if each negative ion causes a decrease of the ionization current. The sensitivity of the detector in this case amounts to 96500 C/mol. A hypercoulometric response is given, if fragments from dissociative processes undergo electron capture at several times and if the enhancing effect of space charges is used. In this case the sensitivity of the ECD exceeds the upper limit given by Faraday's number. The operation conditions of both EGD-modes are described.
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