Study of interaction of polymeric aluminium hydroxide with fluoride
作者:
N. Parthasarathy,
J. Buffle,
W. Haerdi,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1986)
卷期:
Volume 64,
issue 1
页码: 24-29
ISSN:0008-4042
年代: 1986
DOI:10.1139/v86-006
出版商: NRC Research Press
数据来源: NRC
摘要:
The interaction between polymeric aluminium hydroxide, Alp, and fluoride has been investigated to optimize the conditions for removal of fluoride from waste waters of aluminium manufacturing plants using Alp. The results of these studies have shown that the nature of products formed between Alpand fluoride depends on the molar concentration ratio of fluoride to aluminium (rF), pH, and initial fluoride concentration. In the absence of interfering ions, fluoride can be effectively precipitated as Al13(OH)29F10with Alp, usingand 4 < pH ≤ 7. At rF > 1, Alpdissociates and fluoride is precipitated as cryolite, and the residual fluoride concentration is controlled by its high solubility.
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