Synthesis and viscoelastic properties of α,ω‐diquaternary ammonium polybutadiene lonomers
作者:
Caroline Roberts,
W. Edward Lindsell,
Ian Soutar,
期刊:
British Polymer Journal
(WILEY Available online 1990)
卷期:
Volume 23,
issue 1‐2
页码: 55-62
ISSN:0007-1641
年代: 1990
DOI:10.1002/pi.4980230110
出版商: John Wiley&Sons, Ltd
关键词: telechelic;cationomer;polybutadiene;anionic polymerisation;quaternary ammonium
数据来源: WILEY
摘要:
AbstractTelechelic ionomeric elastomers with quaternary ammonium groups (Me2RN+) attached terminally to polybutadiene (M̄n∼ 2.7 × 103; M̄w/M̄n= 1.27; containing 62% 1,4‐linkages) have been synthesised by an anionic technique using a functionalised initiator and terminator, followed by quaternisation of the resulting α,ω‐bis(dimethylamino)polybutadiene. By using differing alkyl halides for quaternisation and by ion exchange chromatography, a series of dialkylated telechelic cationomers has been produced containing alkyl groups, R = Me, Et,n‐Pr,n‐Bu orn‐C5H11with counter anions X = I−, Br−, PF 6−or SO 42−. The glass transition temperatures,Tg, of these cationomers arec.6°C higher than for the precursor, non‐quaternised polymer but are essentially unchanged with variations in groups R or anions X. Dynamic mechanical thermal analyses of the cationomers have been carried out and a secondary transition,Ti, associated with relaxation of ionic cross‐linking interactions, observed. Values ofTidecrease as the size of R increases from C1to C5, and as the anion X is changed from Br−to I−to PF 6−or SO 42−to PF 6−.Activation energies can be derived from the frequency dependence ofTivalues or from the temperature dependence of shift parameters, obtained from the master curves of the dependence on frequency of the shear storage (G') and loss (G') moduli; these activation energies are dependent on the nature of the counter anion, being greatest for the polymer containing the dinegative SO 42−, but are essentially unchanged by the variations in alkyl group, R, implemented in this study. Other results of the dynamic mechanical analyses on the cationomeric elastomers
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