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Comparison of the pitch induced from lamellar and nematic regions in some lyotropic liquid crystal systems

 

作者: M. ACIMIS,   A. AGAR,   A. GOK,  

 

期刊: Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 24, issue 3  

页码: 369-373

 

ISSN:0267-8292

 

年代: 1998

 

DOI:10.1080/026782998207172

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Lamellar phases (Lalpha) composed of decylammonium chloride(DACl), NH4Cl and H2O were doped with cholesteryl-2-ethoxyethoxyethyl carbonate (CEEC) and with (L-MA) or its racemic mixture (DL-MA). Lalpha phases of the novel intrinsic optically active L-serine hydrochloride decylester (L-SDE) and its racemic mixture (DL-SDE) were also prepared. From the chiral Lalpha phases, cholesteric phases (ChD) were induced with increased temperature and it was found that the pitch length shortened as the temperature was raised. This phenomenon is new for micellar cholesterics. The non-chiral Lalpha phases gave pseudo-isotropic and nematic regions with increased temperature. On the basis of these results and those in the literature, a new interpretation of the distorted micelle shape and the formation of the fingerprint texture is presented. The pitches induced from Lalpha regions were always larger than those obtained from nematic regions. From these results it is inferred that the interactions between the micelles in the cholesteric state at room temperature are of 'ideal' type. In addition, the temperature dependence of the pitch in micellar cholesterics is discussed.

 

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