首页   按字顺浏览 期刊浏览 卷期浏览 Polymer Fractionation Calculations Using Refined Free Energy Relations
Polymer Fractionation Calculations Using Refined Free Energy Relations

 

作者: M.T. Rätzsch,   S. Enders,   L. Tschersich,   H. Kehlen,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1991）
卷期: Volume 28, issue 1  

页码: 31-46

 

ISSN:0022-233X

 

年代: 1991

 

DOI:10.1080/00222339108052084

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In an earlier paper, continuous thermodynamics was applied to calculate polymer fractionation procedures leading to lucid equations favorable for computer simulations. The present paper refines that treatment by applying more sophisticated Gibbs free energy relations. The simulation results agree closely with the experimental data, assuming the Flory-Huggins interaction parameter to be a function of the concentration.

 

点击下载:  PDF (585KB)



返 回