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Apparent molal heat capacities and volumes of aqueous electrolytes at 25 °C: NaClO3, NaClO4, NaNO3, NaBrO3, NaIO3, KClO3, KBrO3, KIO3, NH4NO3, NH4Cl, and NH4ClO4

 

作者: Alain Roux,   Goolam M. Musbally,   Gérald Perron,   Jacques E. Desnoyers,   Prem Paul Singh,   Earl M. Woolley,   Loren G. Hepler,  

 

期刊: Canadian Journal of Chemistry  (NRC Available online 1978)
卷期: Volume 56, issue 1  

页码: 24-28

 

ISSN:0008-4042

 

年代: 1978

 

DOI:10.1139/v78-004

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

Measurements at 25 °C with flow calorimeters and densimeters have led to heat capacities and densities of aqueous solutions of 11 1:1 electrolytes: NaClO3, NaBrO3, NaIO3, NaNO3, NaClO4, NH4NO3, KClO3, KBrO3, KIO3, NH4Cl, and NH4ClO4. The first 6 salts were studied up to near saturation. We have used results of these measurements to obtain apparent molal heat capacities and apparent molal volumes of the various solutes. Extrapolation to infinite dilution on the basis of the Debye–Hückel theory bas led toandvalues for each solute. We have compared these standard values with results of earlier investigations.

 

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