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Apparent molal heat capacities and volumes of aqueous electrolytes at 25 °C: NaClO3...
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Apparent molal heat capacities and volumes of aqueous electrolytes at 25 °C: NaClO3, NaClO4, NaNO3, NaBrO3, NaIO3, KClO3, KBrO3, KIO3, NH4NO3, NH4Cl, and NH4ClO4
作者:
Alain Roux,
Goolam M. Musbally,
Gérald Perron,
Jacques E. Desnoyers,
Prem Paul Singh,
Earl M. Woolley,
Loren G. Hepler,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1978)
卷期:
Volume 56,
issue 1
页码: 24-28
ISSN:0008-4042
年代: 1978
DOI:10.1139/v78-004
出版商: NRC Research Press
数据来源: NRC
摘要:
Measurements at 25 °C with flow calorimeters and densimeters have led to heat capacities and densities of aqueous solutions of 11 1:1 electrolytes: NaClO3, NaBrO3, NaIO3, NaNO3, NaClO4, NH4NO3, KClO3, KBrO3, KIO3, NH4Cl, and NH4ClO4. The first 6 salts were studied up to near saturation. We have used results of these measurements to obtain apparent molal heat capacities and apparent molal volumes of the various solutes. Extrapolation to infinite dilution on the basis of the Debye–Hückel theory bas led toandvalues for each solute. We have compared these standard values with results of earlier investigations.
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