Changes in the phase of the barrier to internal rotation upon electronic excitation
作者:
RobertD. Gordon,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1986)
卷期:
Volume 5,
issue 2-3
页码: 121-126
ISSN:0144-235X
年代: 1986
DOI:10.1080/01442358609353372
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Molecules with CX3NO, CX3CHO, and related structures have eclipsed conformations in their ground electronic states, but adopt a staggered equilibrium conformation in theirnn*excited states. This dramatic difference in the torsional barrier in different electronic states of the same molecule is an important clue towards a fuller understanding of the relation between electronic structure and preferred conformation. Results to date are reviewed, and suggestions are made for further experimental and theoretical studies.
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