Disorder in BaTiO3and SrTiO3and the “Ferroelectric” Transition in SrTi18O3
作者:
Robert Blinc,
Bosˇtjan Zalar,
Andrija Lebar,
Mitsuru Itoh,
期刊:
AIP Conference Proceedings
(AIP Available online 1903)
卷期:
Volume 677,
issue 1
页码: 20-25
ISSN:0094-243X
年代: 1903
DOI:10.1063/1.1609933
出版商: AIP
数据来源: AIP
摘要:
A quadrupole coupling induced47Ti and49Ti satellite background is observed in the cubic phases of BaTiO3, SrTiO3and oxygen 18 enriched SrTi18O3. The satellite background demonstrates that all Ti ions are dynamically disordered between several off‐center sites. No splitting or broadening of the central Ti 1/2 → −1/2 NMR transitions is seen on going through the “ferroelectric” transition in SrTi18O3atTc= 25 K. It seems that in contrast to BaTiO3the Ti disorder is still present. © 2003 American Institute of Physics
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