MODELING Cu EXTRACTION FROM ACIDIC SOLUTIONS USING P5100, PT5050, AND LIX 84
作者:
J. H. Russell,
R. L. Rickel,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1990)
卷期:
Volume 8,
issue 6
页码: 855-873
ISSN:0736-6299
年代: 1990
DOI:10.1080/07366299008918035
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The Bureau of Mines studied the extraction of copper (II) from acidic sulfate solutions using commercial extractants LIX 84, P5100, and PT5050. Mathematical models, consisting of sets of nonlinear mass action and mass balance equations, were solved using a commercial equation-solving program on a personal computer. The models suggest that LIX 84 is a mixture of monomelic and dimeric extractant with an extraction equilibrium constant of 145 and a dimerization constant of 65 L/mol; PT5050 appears to be a monomeric extractant with an extraction equilibrium constant of 53; and P5100 shows more complex characteristics, with a monomeric extraction equilibrium constant of 400, a dimer formation constant of 3.7 L/mol, and a modifier-complex formation constant of 5.8 L/mol. For all models, the relative error of fit was less than 6%.
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