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RAPID BROWNIAN COAGULATION IN DILUTE POLYDISPERSE EMULSIONS

 

作者: NataliaA. Mishchuk,   SvetlanaV. Verbich,   StanislavS. Dukhin,   Øystein Holt,   Johan Sjöblom,  

 

期刊: Journal of Dispersion Science and Technology  (Taylor Available online 1997)
卷期: Volume 18, issue 5  

页码: 517-537

 

ISSN:0193-2691

 

年代: 1997

 

DOI:10.1080/01932699708943754

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In this experimental investigation of rapid Brownian coagulation in dilute oil-in-water emulsions, the absence of deformation influence on droplet interaction and drainage is established. The result is in agreement with the theory of Brownian coagulation in miniemulsions proposed by the Borwankar-Ivanov group. As a first approximation the applicability of Smoluchowski theory to rapid coagulation in emulsions is established. Observing the weak influence of droplet deformation on rapid coagulation and taking into account Borwankar-Ivanov theory that the transition to charged droplets and lower electrolyte concentrations decreases the droplet deformation, we conclude that both slow coagulation and the reversible one cannot be influenced by droplet deformation in miniemulsions. A droplet surface is homogenous in contrast to solid particle surfaces. Thus emulsions can be used as a

 

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