Copolymers like 8-hydroxyquinoline-furfural, 2,4-dihydroxyacetophenone-furfural, β-resorcylic acid-furfural, anthranilic acid-furfural, and salicylic acid-furfural are well-known polymeric ligands [1–4], and their ion-exchange properties have been reported. In the present paper, we report the preparation and characterization of β-resorcylaldehyde-furfural (RAF) polymer and its polychelates with the bivalent metal ions CU2+, Ni2+, Co2+, Mn2+, and Zn2+.