首页   按字顺浏览 期刊浏览 卷期浏览 Thermally Stable Arylpalladium Diamine Complexes as Versatile Precursors in Organopalla...
Thermally Stable Arylpalladium Diamine Complexes as Versatile Precursors in Organopalladium Chemistry; Synthesis and X‐Ray Molecular Structure of PdIPh(tmeda) and its Conversion to PdMePh(tmeda) {tmeda = Me2N(CH2)2NMe2}

 

作者: Wim de Graaf,   John van Wegen,   Jaap Boersma,   Gerard van Koten,   Anthony L. Spek,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1989）
卷期: Volume 108, issue 7‐8  

页码: 275-277

 

ISSN:0165-0513

 

年代: 1989

 

DOI:10.1002/recl.19891080707

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe new complex PdIPh(tmeda) (1) (tmeda = Me2N(CH2)2NMe2) was prepared by oxidative addition of iodobenzene to {bis(dibenzylideneacetone)}palladium(0) in the presence of tmeda and has been characterized by NMR spectroscopy and X‐ray crystallography. Treatment with MeLi affords the remarkably stable mixed diorgano species PdMePh(tmeda) (2). Both (1) and (2) are useful precursors to other organopalladium species by ligand exchange reaction

 

点击下载:  PDF (239KB)



返 回