首页   按字顺浏览 期刊浏览 卷期浏览 Dielectric Relaxations of a Side Chain Liquid Crystal Homopolymer and Copolymer
Dielectric Relaxations of a Side Chain Liquid Crystal Homopolymer and Copolymer

 

作者: R.B. Akins,   Z.Z. Zhong,   W.L. Gordon,   D.E. Schuele,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 258, issue 1  

页码: 15-26

 

ISSN:1058-725X

 

年代: 1995

 

DOI:10.1080/10587259508034544

 

出版商: Taylor & Francis Group

 

关键词: Liquid crystal polymer;dielectric relaxation;glass transition;polymer backbone;Fuoss–Kirkwood function

 

数据来源: Taylor

 

摘要:

The dielectric loss spectrum of a side chain liquid crystal polymer (SCLCP) has been measured from 10 Hz to 100 kHz in the smectic phase. Three liquid crystalline siloxane polymers are examined, a homopolymer and two random copolymers, all of which contain a chiral smectic mesogen and an eleven-methylene spacer in the side chain. Two dielectric relaxations have been observed, the high-frequency α and low-frequency δ processes. The effect of the copolymer morphology in these SCLCPs is to increase the dielectric relaxation strength of the δ process relative to the α process and to cause increased overlap between the two peaks. These two observations suggest that the copolymer structure aids large scale reorientations in the δ process because of increased cooperativity with the backbone.

 

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