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Mechanistic aspects of the fluorination of cyclohexane and cyclohexene with acetyl hypofluorite in acetic acid

 

作者: G. W. M. Visser,   J. D. M. Herscheid,   A. Hoekstra,   C. N. M. Bakker,   B. W. V. Halteren,   G. A. Brinkman,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1986）
卷期: Volume 105, issue 7‐8  

页码: 214-219

 

ISSN:0165-0513

 

年代: 1986

 

DOI:10.1002/recl.19861050703

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe reaction of acetyl hypofluorite in acetic acid with both cyclohexane and cyclohexene has been investigated. Analysis by GCMS and radio‐HPLC, using18F as a tracer, revealed that, apart from typical products expected from a radical reaction, several compounds originating from carbocationic intermediates were formed. On the basis of the observed products, a single‐electrontransfer (SET) mechanism leading to an intermediate radical‐cation is pro

 

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