Lyotropic phase behaviour of disc-shaped tetra-palladium organyls in apolar organic solvents [1]
作者:
N. Usol'tseva,
K. Praefcke,
D. Singer,
B. Gündogan,
期刊:
Liquid Crystals
(Taylor Available online 1994)
卷期:
Volume 16,
issue 4
页码: 601-616
ISSN:0267-8292
年代: 1994
DOI:10.1080/02678299408036533
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The lyomesomorphic behaviour in apolar organic solvents of members of two series1and2of disc-shaped palladium organyls—the syntheses of four of them are new (1d, fand2a, e) and are described here—each carrying twelve long lipophilic chains have been studied. Their lyomesomorphism appeared to be complex and has been observed here for the first time with metal organyls. As can be seen by polarizing microscopy, most of the binary mixtures investigated here exhibitnematicproperties. For two members of series1—the chloro-bridged1band its bromo-analogue1c—there is even evidence for the existence oftwodifferent nematic lyomesophases side by side showing reversible transitions between them. In ternary systems, i.e. after the addition of 2,4,7-trinitrofluorenone (TNF, a strong electron acceptor), the nematic phases are stabilized, suggesting that their mesophase structures are made up by columns with intercalated TNF molecules (charge transfer complex formation). Influences of structural features of the pallado-mesogens on the one hand and of the type of solvent on the other on the molecular self-aggregation in the observed types of lyotropic mesophase formed are discussed in detail.
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