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Field‐frequency locked X‐band Overhauser effect spectrometer

 

作者: N. Chandrakumar,   P. T. Narasimhan,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1981)
卷期: Volume 52, issue 4  

页码: 533-538

 

ISSN:0034-6748

 

年代: 1981

 

DOI:10.1063/1.1136634

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The design and construction of an Overhauser Effect Spectrometer operating at X band is described. The ESR section is a Varian V‐4502 spectrometer equipped with a 9‐in. electromagnet and a shim coil assembly. NMR detection is based on a broadband rf hybrid juction feeding a coil in an X‐band quartz dielectric cavity. Signal processing is carried out at a constant intermediate frequency of 25.1 MHz with a Varian V‐4311 fixed frequency rf unit. The mixing scheme employed to translate the NMR information to 25.1 MHz is described. Medium resolution performance (resolution ∼10−6) for the NMR is achieved under field‐frequency locked conditions. The lock is based on a Super‐Regenerative Oscillator (SRO) housing a control sample, and operating as a field‐tracking frequency source. This SRO injects into an oscillator which excites the analytical sample resonance and also serves as a local oscillator, thereby making the locked spectrometer multinuclear in capability. Typical Overhauser effect recordings of protons and fluorines are presented.

 

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