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Application of Continuous Thermodynamics to Polymer Fractionation

 

作者: M.T. Ratzsch,   H. Kehlen,   L. Tschersich,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1989)
卷期: Volume 26, issue 7  

页码: 921-935

 

ISSN:0022-233X

 

年代: 1989

 

DOI:10.1080/00222338908052021

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Continuous thermodynamics was developed in recent years and applied successfully to the liquid-liquid equilibrium of poly disperse polymer solutions. Continuous thermodynamics is based on the direct use of continuous distribution functions in the thermodynamic equations. There is no need for a reduction to pseudocomponents. This paper presents the application of continuous thermodynamics to successive polymer fractionation procedures based on solubility differences. In this way, simple equations for the distribution function of the different polymer fractions are obtained. Furthermore, the other equations describing the fractionation possess a lucid structure favorable for computer simulations of the fractionation procedures.

 

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