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Spin dynamics and magnetic ordering in mixed valence systems

 

作者: S. M. Shapiro,   H. B. Mo&slash;ller,   J. D. Axe,   R. J. Birgeneau,   E. Bucher,  

 

期刊: Journal of Applied Physics  (AIP Available online 1978)
卷期: Volume 49, issue 3  

页码: 2101-2106

 

ISSN:0021-8979

 

年代: 1978

 

DOI:10.1063/1.324753

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Neutron scattering measurements are reported on the mixed valence compounds Ce1−xThxand TmSe. The &khgr;″(Q,&ohgr;) as derived from the inelastic spectra of Ce0.74Th0.26shows a peak in the &ggr; phase near 20.0 meV and shifts abruptly to greater than 70.0 meV at the transition to the &agr; phase. The temperature independence of the susceptibility within the &ggr; phase cannot be simply reconciled with the temperature dependence of the valence within the &ggr; phase. TmSe is shown to order in a type I antiferromagnetic structure belowTN∼3.2 K. The magnetic phase diagram is understood as a successive domain reorientation and a metamagnetic phase transition forT<3 K with increasing field. The mixed valence nature manifests itself in a reduced moment and a markedly altered crystal field. Another sample of TmSe with a lattice parameter implying 100&percent; Tm3+exhibits spin correlations characteristic of a type II structure but never achieves long range order.

 

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