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Kinetic theory and transport phenomena for a dumbbell model under nonisothermal conditions

 

作者: Hans Christian Öttinger,   Fabrizio Petrillo,  

 

期刊: Journal of Rheology  (AIP Available online 1996)
卷期: Volume 40, issue 5  

页码: 857-874

 

ISSN:0148-6055

 

年代: 1996

 

DOI:10.1122/1.550765

 

出版商: The Society of Rheology

 

关键词: Kinetic theory;Transport phenomena;Nonisothermal flow;Dumbbell model;Heat‐flux vector;POLYMERS;SOLUTIONS;TRANSPORT THEORY;BROWNIAN MOVEMENT;HEAT FLUX;DIFFUSION;KINETIC EQUATIONS

 

数据来源: AIP

 

摘要:

A Hookean dumbbell model for polymers in dilute solutions undergoing homogeneous flow is generalized to include arbitrary imposed temperature profiles. In order to obtain the ‘‘nonisothermal diffusion equation’’ for the probability density in polymer configuration space we generalize the approach of Schieber and Öttinger [J. Chem. Phys.89, 6972–6981 (1988)] to Brownian motion out of equilibrium. In addition, we derive the polymer contributions to the mass‐flux vector, stress tensor and heat‐flux vector by means of the kinetic theory approach of Curtiss and Bird [Adv. Polym. Sci.125, 1–101 (1996)] for the case of a slowly varying temperature gradient, and we find coupled constitutive equations for the mass, momentum and energy fluxes. For a simple steady shear flow it is then possible to calculate the heat‐flux vector explicitly, at least for small temperature gradients and shear rates. We compare our approach and results with previous works on this subject, and we finally discuss some extensions.

 

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