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Gap‐dependence of the viscosity of a thermotropic liquid crystalline copolymer

 

作者: Douglass S. Kalika,   Laurent Nuel,   Morton M. Denn,  

 

期刊: Journal of Rheology  (AIP Available online 1989)
卷期: Volume 33, issue 7  

页码: 1059-1070

 

ISSN:0148-6055

 

年代: 1989

 

DOI:10.1122/1.550007

 

出版商: The Society of Rheology

 

关键词: VISCOSITY;LIQUID CRYSTALS;COPOLYMERS;SHEAR;ORGANIC ACIDS;HYDROXY COMPOUNDS;RHEOLOGY

 

数据来源: AIP

 

摘要:

We have measured the shear and complex viscosities of a thermotropic liquid crystalline copolymer ofp‐hydroxybenzoic acid and 2,6‐hydroxynaphthoic acid as a function of capillary diameter and parallel‐plate gap spacing. In constrast to a study by Wissbrun, Kiss, and Cogswell, who reported that the viscosity increases significantly at small gaps, we find no dependence on the capillary diameter and a smalldecreasein complex viscosity with parallel‐plate spacing. In an appendix we address an experimental artifact that can lead to an apparent decrease of the viscosity with gap spacing even for flexible polymers.

 

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