cis-trans-isomerism of the peptide bond in N-methylated alanine dipeptides
作者:
S.L.Portnova,
V.F.Bystrov,
T.A.Balashova,
V.T.Ivanov,
Yu.A.Ovchinnikov,
期刊:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
(Springer Available online 2004)
卷期:
Volume 19,
issue 4
页码: 776-780
ISSN:0568-5230
年代: 2004
DOI:10.1007/BF00867232
出版商: Springer_US-Boston
数据来源: Springer
摘要:
1.cis-trans-Isomerism of the N-methylamide bond in depeptides containing N-methylalanine residues was studied.2.Approximately 20% of the dipeptides with a N-methylamide bond have a cis-configuration.3.The thermodynamic parameters of the cis-trans-transition were determined.
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