AbstractEthyl hexyl esters of oleic, linoleic, and linolenic acids were synthesised and thermally polymerised to obtain products with viscosities in the range of hydrocarbon lubricants at 100°C (11–22 cSt). Molecular weight, elemental analysis, IR,13C NMR, and intrinsic viscosity data showed that most of these derivatives are mixtures of monomers, dimers, and trimers and have linear and cyclic products with predominantly trans characteristics.The lubricity characteristics were determined on a friction and wear tester under conditions of thick‐film lubrication. A comparison was made with hydrocracked hydrocarbon lubricants of comparable viscosities at 100°C and comparable viscosity indices.It is inferred that all the esters maintained relatively thicker surface films and much lower friction coefficients than the hydrocarbon oils. The wear‐scar data show that the antiwear characteristics of polymerised ethyl hexyl oleate and linoleate are only slightly inferior to those of the hydrocarbon oils, but at higher temperatures their antiwear characteristics rapidly deteriorate while the friction coefficients markedly increase and become comparable to those of hydrocarbon oils. These studies are being undertaken with a view to selecting and modifying vegetable oils containing mixtures of fatty acids for obtaining esters of outstanding friction, wear, and film‐forming charac