Sampling and Ion Chromatographic Analysis of Pyruvic Acid and Methane Sulfonic Acid in Air
作者:
Daniel Grosjean,
J.Dirk Nies,
期刊:
Analytical Letters
(Taylor Available online 1984)
卷期:
Volume 17,
issue 2
页码: 89-96
ISSN:0003-2719
年代: 1984
DOI:10.1080/00032718408065268
出版商: Taylor & Francis Group
关键词: puruvic acid;methane sulfonic acid;ion chromatography;atmospheric photochemistry
数据来源: Taylor
摘要:
Pyruvic acid and methane sulfonic acid, both products of photochemical reactions in air, are quantitated by ion chromatography analysis in borate and carbonate buffer, respectively, following sampling with impingers and Teflon filters. Detection limits are 50 and 80 nanogram/mL for pyruvate and sulfonate ions, respectively, and correspond to ∼2-3 parts per billion (gas phase) and ∼1 μg m−3(particulate phase) in air. Other ionic species present as co-products in polluted air, including nitrate, sulfate, chloride, carbonate, formate and acetate do not interfere with the pyruvate and sulfonate measurements.
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