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Nitrogen depletion during oxidation inN2O

 

作者: N. S. Saks,   D. I. Ma,   W. B. Fowler,  

 

期刊: Applied Physics Letters  (AIP Available online 1995)
卷期: Volume 67, issue 3  

页码: 374-376

 

ISSN:0003-6951

 

年代: 1995

 

DOI:10.1063/1.114633

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The incorporation of nitrogen in oxides has been studied after furnace oxidation inN2O at 900 °C. We observe that nitrogen isremovedfrom the oxide bulk during oxidation inN2O, while simultaneously nitrogen is incorporated at the growingSi–SiO2interface. This results suggests that nitrogen incorporation involves a dynamic equilibrium between competing processes which causes both nitrogen incorporation and depletion. A chemical model for nitrogen removal is proposed based on a reaction with NO. Reaction energies, estimated from semiempirical quantum‐mechanical calculations, support the proposed model. ©1995 American Institute of Physics.

 

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