Nitrogen depletion during oxidation inN2O
作者:
N. S. Saks,
D. I. Ma,
W. B. Fowler,
期刊:
Applied Physics Letters
(AIP Available online 1995)
卷期:
Volume 67,
issue 3
页码: 374-376
ISSN:0003-6951
年代: 1995
DOI:10.1063/1.114633
出版商: AIP
数据来源: AIP
摘要:
The incorporation of nitrogen in oxides has been studied after furnace oxidation inN2O at 900 °C. We observe that nitrogen isremovedfrom the oxide bulk during oxidation inN2O, while simultaneously nitrogen is incorporated at the growingSi–SiO2interface. This results suggests that nitrogen incorporation involves a dynamic equilibrium between competing processes which causes both nitrogen incorporation and depletion. A chemical model for nitrogen removal is proposed based on a reaction with NO. Reaction energies, estimated from semiempirical quantum‐mechanical calculations, support the proposed model. ©1995 American Institute of Physics.
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