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Simple electrochemical synthesis of vanadium(II) halides

 

作者: Jacob J. Habeeb,   Lynn Neilson,   Dennis G. Tuck,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1977）
卷期: Volume 55, issue 14  

页码: 2631-2633

 

ISSN:0008-4042

 

年代: 1977

 

DOI:10.1139/v77-365

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

Vanadium metal dissolves rapidly in a cell Pt/X2in CH3CN/V (anode) (X = Cl, Br, I) under applied voltages of 5–50 V. The solution phase yields crystalline VCl2. 2CH3CN, VBr2. CH3CN, or VI2; the acetonitrile adducts decompose to VX2on heating in vacuo. Overall yields of VX2, based on weight of metal dissolved, are 80–90%.

 

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