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Relation between stress relaxation and aging resistance of rubber vulcanizates—some preliminary investigations

 

作者: Holger Leth Pedersen,   Bent Nielsen,  

 

期刊: Journal of Polymer Science  (WILEY Available online 1951)
卷期: Volume 7, issue 2‐3  

页码: 97-103

 

ISSN:0022-3832

 

年代: 1951

 

DOI:10.1002/pol.1951.120070201

 

出版商: Interscience Publishers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractIn this paper some details are given for the construction of a simple balance for the measurement of stress relaxation at constant elongation. A simple means of obtaining equal strain in the two parts of the strained specimen is provided. By means of four typical stocks covering the widest possible range of aging resistance it is shown that the stress relaxations give approximately the same estimate of stability as does the normal Geer test using 2 mm. dumbbell specimens. As a measure for stress relaxation the time is used that is required to obtain 50% of the value of the interpolated modulus at 200% elongation 6 seconds after the straining zero time at 110°C. The parameter for the aging test is the time in days at 70°C. for the 50% value of tensile strengths. The range for the stress relaxation parameter may be estimated to 8–1200 min. and the aging parameter from 10–600 days. Finally the concordance of temperature coefficient for relaxation and oxidation rates is

 

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