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THE SYSTEM SILVER–INDIUM–GALLIUM

 

作者: A. N. Campbell,   W. F. Reynolds,  

 

期刊: Canadian Journal of Chemistry  (NRC Available online 1962)
卷期: Volume 40, issue 1  

页码: 37-45

 

ISSN:0008-4042

 

年代: 1962

 

DOI:10.1139/v62-007

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The system silver–indium–gallium has been investigated by the standard techniques of thermal analysis, photomicrography, X-ray photography, and hardness testing. The smallness of the heat effects made the determination of the liquid surface indefinite, at least in the low-temperature region where the pronounced tendency for metastable liquid phase to persist rendered all measurements indefinite, but the room-temperature isotherm was determined with more certainty. Owing to the complexity of the diagram there is still some uncertainty about some areas.A one-phase area (α phase) exists in the silver-rich region of the ternary isotherm, representing the solid solubility of indium and gallium in silver. The silver-rich intermediate phase in the system silver–indium, δ, is shown to have a close-packed hexagonal structure and its lattice constants have been determined. The structure of γ, the corresponding phase in the system silver–gallium is more complex and was not determined. δ and γ phases do not form a continuous one-phase region.Ternary peritectics exist at 623 °C and 600 °C (approximately). It is possible that two peritectics exist at the latter temperature, in close proximity.The ternary eutectic lies at 14.5 °C and has an approximate composition of 2% silver, 24% indium, and 74% gallium.

 

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